SHAKE SATELLITES IN THE L(2,3)VV AUGER SPECTRUM OF THE HCL MOLECULE

The L2.3VV Auger spectrum of HCI is calculated with shake satellites ( SS) L2,3V-VVV. Included in the calculation are the ligand electron den sity in the calculation of Auger rates, the spin-orbital splitting of the initial Cl2p level, the multiplet splitting of the final states an d the final states interaction. The only empirical parameters used in the calculation are molecular orbitals ionization potentials. Good agr eement with experiment is obtained. The spectral feature at 159-163 eV is assigned to predominantly SS transitions.