BIS(1-METHYLCYTOSINIUM) TETRACHLOROCOBALTATE(II), (C5H8N3O)2[COCL4]

Citation
Ec. Hillgeris et B. Lippert, BIS(1-METHYLCYTOSINIUM) TETRACHLOROCOBALTATE(II), (C5H8N3O)2[COCL4], Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 670-671
Citations number
10
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
5
Pages
670 - 671
Database
ISI
SICI code
0108-2701(1994)50:<670:BT(>2.0.ZU;2-K
Abstract
The 1-methylcytosinium cations (4-amino-2-oxo-1,2-dihydro-3H+-pyrimidi nium) are protonated at N3. The tetrachlorocobaltate anion has distort ed tetrahedral geometry with average Co-Cl bonds of 2.27 (1) angstrom and Cl-Co-Cl angles in the range 104.7-117.6-degrees.