PENTAAQUA(2-FURANCARBOXYLATO)NICKEL(II) 2-FURANCARBOXYLATE AT 120-K

Citation
B. Paluchowska et al., PENTAAQUA(2-FURANCARBOXYLATO)NICKEL(II) 2-FURANCARBOXYLATE AT 120-K, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 683-686
Citations number
10
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
5
Pages
683 - 686
Database
ISI
SICI code
0108-2701(1994)50:<683:P2A1>2.0.ZU;2-G
Abstract
The crystal structure of [Ni(C5H3O3)(H2O)5](C5H3O3) has been determine d by X-ray diffraction at 120 K. One 2-furancarboxylate anion and five water molecules are involved in formation of a distorted octahedron a round the Ni atom. The Ni-O bond lengths range from 2.019 (3) to 2.090 (3) angstrom. The second anion is linked to the complex cation by bif urcated hydrogen bonds. There is no significant difference between the geometries of the coordinated and uncoordinated anions.