MU-3-(O,O'-DIETHYL DITHIOPHOSPHATO-2-KAPPA-S,3 4-KAPPA-2S')-DI-MU-3-SULFIDO-1/2/3-KAPPA-3S LFIDO-1-KAPPA-S-TRIS(TRIPHENYLPHOSPHINE)-2-KAPPA-P 3-KAPPA-P 4-KAPPA-P-MOLYBDENUMTRISILVER/

Authors
DU SW WU XT
Citation
Sw. Du et Xt. Wu, MU-3-(O,O'-DIETHYL DITHIOPHOSPHATO-2-KAPPA-S,3 4-KAPPA-2S')-DI-MU-3-SULFIDO-1/2/3-KAPPA-3S LFIDO-1-KAPPA-S-TRIS(TRIPHENYLPHOSPHINE)-2-KAPPA-P 3-KAPPA-P 4-KAPPA-P-MOLYBDENUMTRISILVER/, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 700-702
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
5
Pages
700 - 702
Database
ISI
SICI code
0108-2701(1994)50:<700:MD4>2.0.ZU;2-T
Abstract
The structure of the title compound, [MoAg3S4(C4H1002PS2)(C18H15P)3], contains an incomplete cubane-like cluster core, [MoAg3(C4H10O2PS2)S3] 2+, in which a diethyl dithiophosphategroup acts as a triply bridging ligand to coordinate three Ag atoms with bond lengths of 2.626 (4) [Ag -(1)-S(6)], 2.690 (4) [Ag(2)-S(5)] and 2.698 (4) angstrom [Ag(3)-S(5)] /