A COPPER(II) COMPLEX OF THE DEPROTONATED ANION OF (2R,10R)-N,N'-DIALANYLPROPYLENEDIAMINE

Authors
TAHIROV TH LU TH SHU K CHUNG CS
Citation
Th. Tahirov et al., A COPPER(II) COMPLEX OF THE DEPROTONATED ANION OF (2R,10R)-N,N'-DIALANYLPROPYLENEDIAMINE, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 710-712
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
5
Pages
710 - 712
Database
ISI
SICI code
0108-2701(1994)50:<710:ACCOTD>2.0.ZU;2-X
Abstract
The title compound, ',N''-propylenediaminato(2-)-kappa2N,N']copper(II) dihydrate, [Cu(C9H18N4O2)(H2O)].2H2O, in which two amide protons of ( 2R, 10R)-N,N'-dialanylpropylenediamine are released, exists as a monom eric complex. The Cu(II) ion is five-coordinate with distorted square- pyramidal geometry; the water O atom is in an axial position and two a mine and two deprotonated amide N atoms are in equatorial positions. A ll three water molecules, two amine groups and two carbonyl O atoms pa rticipate in forming hydrogen bonds.