STRUCTURAL INVESTIGATIONS OF A TETRACYCLIC ENDO-NORBORENYL DERIVATIVE

Authors
LLOYD BA ARIF AM COOTS RJ ALLRED EL
Citation
Ba. Lloyd et al., STRUCTURAL INVESTIGATIONS OF A TETRACYCLIC ENDO-NORBORENYL DERIVATIVE, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 777-781
Citations number
25
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
5
Pages
777 - 781
Database
ISI
SICI code
0108-2701(1994)50:<777:SIOATE>2.0.ZU;2-#
Abstract
The X-ray crystal structure of racyclo-[6.2.1.1(3.6).0(2,7)]dodec-9-en -anti-11-yl p-bromobenzoate, C19H19BrO2 (1), was determined at 148 K. The molecule consists of norbornene with an anti-p-bromobenzoate subst ituent at the methano bridge and an exo-norbornyl unit endo-fused to t he ethano bridge. Structural comparisons are made with another derivat ive and steric interactions examined. The distance from the norbornyl methano bridge to the norbornene etheno bridge is consistent with lati cyclic hyperconjugation in (1).