STRUCTURAL COMPARISONS OF A PERPENDICULAR DIENE WITH KNOWN DERIVATIVES

Authors
LLOYD BA ARIF AM ALLRED EL
Citation
Ba. Lloyd et al., STRUCTURAL COMPARISONS OF A PERPENDICULAR DIENE WITH KNOWN DERIVATIVES, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 781-784
Citations number
15
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
5
Pages
781 - 784
Database
ISI
SICI code
0108-2701(1994)50:<781:SCOAPD>2.0.ZU;2-R
Abstract
The X-ray crystal structure determination of endo,exo-12-methylenetetr acyclo[6.2. 1.1(3,6).0(2,7)]dodec-9-en-anti-11-yl p-bromobenzoate, C20 H19BrO2 (1), is reported. The molecule consists of norbornene with an anti-p-bromobenzoate substituent at the methano bridge and an exo-meth ylenenorbomyl unit endo-fused to the ethano bridge. The ring C atom of the exocyclic double bond is pyramidalized significantly. Steric inte ractions are examined and some structural comparisons are made with ot her derivatives.