AMINO-ACID COORDINATION TO CHROMIUM(III) WITH MERIDIONAL GEOMETRY

Authors
SUBRAMANIAM V HOGGARD PE
Citation
V. Subramaniam et Pe. Hoggard, AMINO-ACID COORDINATION TO CHROMIUM(III) WITH MERIDIONAL GEOMETRY, Journal of coordination chemistry, 31(2), 1994, pp. 157-165
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
31
Issue
2
Year of publication
1994
Pages
157 - 165
Database
ISI
SICI code
0095-8972(1994)31:2<157:ACTCWM>2.0.ZU;2-P
Abstract
L-lysine and L-glutamic acid can be made to coordinate as tridentate l igands with meridional geometry in octahedral mixed ligand complexes w here the other ligand is tridentate and has a preference for meridiona l coordination. Both Cr(dpt)(L-lys)]2+ (Hlys - lysine, dpt - di(3-amin opropyl)amine) and [Cr(glygly)(L-glu)]- (H-2glygly - glycylglycine, H- 2glu - glutamic acid) exhibit meridional geometry.