The Lubin-Sieroszowice mining district is a world-class copper-silver,
stratabound ore deposit that lies near the Lower-Upper Permian bounda
ry. It transgresses the Werra dolomite, the Kupferschiefer organic ric
h shale and the Weissliegendes sandstone, which overlie barren Rotlieg
endes sandstone. On the basis of underground and microscope observatio
ns and light stable isotope data, and thermodynamic calculations, a ne
w ore genesis model is proposed whereby ore minerals were deposited in
the following stages: Stage 0 was synsedimentary or earliest diagenet
ic and contains 100s ppm of base metals trapped by clay minerals, and
minor sulphides. Stage I was early diagenetic and contains 1000s ppm b
ase metals. It is characterized by bornite and overlying chalcopyrite
+ pyrite that lie a short distance above the Rotliegendes/Weissliegend
es contact. The sulphides were deposited near the interface between an
overlying, buffered, reducing fluid (1), largely derived from the Kup
ferschiefer, and an oxidizing fluid (2) in the Rotliegendes. Stage II
is the main ore-forming stage. This stage is late diagenetic, peneconc
ordant, lies near the Kupferschiefer/Weissliegendes contact, and conta
ins several percent base metals. It is associated with the hematite-be
aring Rote Faule facies and is characterized by vertical zonation. A c
entral chalcocite zone is flanked above and below by bornite and chalc
opyrite. Silver occurs with all the above sulphides. Galena and sphale
rite occur mainly just above copper zone, whereas pyrite is usually pr
esent in the upper part of the copper zone and together with galena an
d sphalerite. Metals were transported in a copper-rich oxidizing fluid
(3), which probably originated deep in the Permian basin, reacted wit
h organic matter in the Kupferschiefer, and mixed with reducing fluid
(1) in the Weissliegendes, resulting in the observed mineral zonation.
Stage III is late diagenetic, discordant and is represented by massiv
e and dispersed chalcocite ore present on the peripheries and below an
hydrite-cemented Weissliegendes sandstone. It resulted from redistribu
tion of earlier copper and silver minerals by descending, reduced, sul
phur-rich fluids (4), Stage IV consists of rare polymetallic veins of
no economic importance that cut the stratigraphy and are probably rela
ted to Alpine tectonism. The richest and thickest ore is in the Weissl
iegendes, 10-15 km east of the Rote Faule facies (Fig. 1). It probably
occupies structures that trapped fluid (1) which was the main precipi
tant of metals in the sandstone.