The aroma fraction of Parmesan cheese was studied on 21 samples of cer
tified origin and aging. Volatile compounds were isolated using the dy
namic headspace and simultaneous distillation-extraction techniques an
d analyzed by means of GC and GC-MS. A total of 167 compounds were ide
ntified: hydrocarbons (23), aldehydes (19), ketones (19), alcohols (29
), esters (24),and acids (25) are the prevalent classes of substances.
With the headspace technique the most volatile compounds were sampled
, whereas the distillation-extraction technique was Suitable even for
long-chain carbonyl derivatives, acids, esters, and lactones, which ar
e known to be important components of the flavor. In addition, free fa
tty acids and the volatile products of the lactic fermentation (ethano
l, acetaldehyde, diacetyl, and acetoin) were determined.