F. Rosemunch et al., CONFORMATIONAL STUDY OF THE COMPLEX ETA(6 )-(4-(TRIFLUOROMETHOXY)ANILINE)TRICARBONYLCHROMIUM, Journal of organometallic chemistry, 470(1-2), 1994, pp. 131-135
Conformational study of 6-(4-(trifluoromethoxy)aniline)tricarbonylchro
mium shows in the solid state that the trifluoromethoxy group is nearl
y perpendicular to the arene ring (CF3-C-O = 117-degrees) and that the
amino group is eclipsed by a chromium carbonyl bond, conformation whi
ch is also found in solution.