ANALOGS OF DIOP - SYNTHESIS, REACTIVITY, AND NMR BEHAVIOR

Authors
BORNER A KADYROV R MICHALIK M HELLER D
Citation
A. Borner et al., ANALOGS OF DIOP - SYNTHESIS, REACTIVITY, AND NMR BEHAVIOR, Journal of organometallic chemistry, 470(1-2), 1994, pp. 237-242
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
470
Issue
1-2
Year of publication
1994
Pages
237 - 242
Database
ISI
SICI code
0022-328X(1994)470:1-2<237:AOD-SR>2.0.ZU;2-Q
Abstract
The methyl)-2-(alpha-naphthoxy)-1,3,2-dioxaphospholane (1) and thyl)-2 -dimethylamino-2-oxo-1,3,2-dioxaphospholane (2), analogues of the chir al bisphosphine ligand DIOP, have been synthesized. Both compounds hav e a second phosphorus functionality in the backbone of the chiral bisp hosphine. That the reactivities of the various phosphorus atoms in 1 a re different was shown for the reaction with BH3. The complexation beh aviour of 1 towards Rh(I) was studied with the aid of P-31 NMR spectro scopy.