ELIMINATION OF BETA-PALLADIUM HYDROXIDE IN THE PD(II)-CATALYZED REACTION OF METHYL (ALPHA-HYDROXYMETHYL)ACRYLATE WITH ALCOHOLS

Citation
T. Hosokawa et al., ELIMINATION OF BETA-PALLADIUM HYDROXIDE IN THE PD(II)-CATALYZED REACTION OF METHYL (ALPHA-HYDROXYMETHYL)ACRYLATE WITH ALCOHOLS, Journal of organometallic chemistry, 470(1-2), 1994, pp. 253-255
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
470
Issue
1-2
Year of publication
1994
Pages
253 - 255
Database
ISI
SICI code
0022-328X(1994)470:1-2<253:EOBHIT>2.0.ZU;2-9
Abstract
Exclusive elimination of beta-Pd-OH takes place in the oxypalladation intermediate derived from methyl (a-hydroxymethyl)acrylate and alcohol s with PdCl2 catalyst, and no beta-Pd-H elimination occurs.