The role of both Field Ion Microscopy and Atom-Probe techniques in the
investigation of solid state phase transformations is discussed on th
e basis of some examples. The first illustration deals with Long Perio
d Superstructures observed in Cu3 Pd system. Atom-probe investigations
conducted on (001) planes show the occurence of Long Range Order modu
lations in the vicinity of antiphase boundaries. Because of its very h
igh spatial resolution, atom-probe is also an attractive tool for the
study of unmixing processes. Some results related to the spinodal deco
mposition of the iron-chromium system are discussed in connection with
current unmixing theories. Prospects opened by the emergence of new t
hree-dimensional atom-probes are given.