H. Tsubakihara et al., SURFACE CONDUCTIVITY OF POLYIMIDE FILMS M ODIFIED BY KRF EXCIMER-LASER IRRADIATION, Kobunshi ronbunshu, 51(5), 1994, pp. 361-363
The surface conductivity of PI (polyimide, U-Film N) irradiated by the
KrF excimer laser increased with increasing laser fluence. As the irr
adiation progressed, the surface morphology changed from a relatively
smooth to a granular structure. SEM analysis showed that the amplitude
and spacing of the surface roughness increased with increasing laser
energy. The XPS analysis of laser irradiated surface revealed the loss
of oxygen and nitrogen. All the results are interpreted in terms of t
he carbonization of PI, which leads to the occurrence of surface condu
ctivity induced by KrF laser ablation.