METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .72. HALF-SANDWICH IRIDIUM(III) AND RUTHENIUM(II) COMPLEXES WITH DIANIONS OF 2-HYDROXYIMINOCARBOXYLIC ACIDS

Authors
BERGS R LAMPEKA R ROBL C BECK W
Citation
R. Bergs et al., METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .72. HALF-SANDWICH IRIDIUM(III) AND RUTHENIUM(II) COMPLEXES WITH DIANIONS OF 2-HYDROXYIMINOCARBOXYLIC ACIDS, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 49(4), 1994, pp. 483-488
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
49
Issue
4
Year of publication
1994
Pages
483 - 488
Database
ISI
SICI code
0932-0776(1994)49:4<483:MOBIL.>2.0.ZU;2-9
Abstract
Chiral chelate complexes with dianions of 2-hydroxyiminocarboxylic aci ds (mu(5)-Cp)(Do)Ir-N(O)=C(R)CO2 (1) und (mu(6)-p-cymene)(Do)Ru-N(O)= C(R)CO2 (2) are obtained by deprotonation of the compounds (mu(5)-Cp) (Cl)Ir-N(OH)=C(R)CO2 and (mu(6)-p-cymene)(Cl)Ru-N(OH)=C(R)CO2 in the p resence of a donor ligand (Do = PR(3), P(OMe)(3), py). The structure o f (mu(5)-Cp)(Me(3)P)Ir-N(O)=C(Me)CO2 has been determined by X-ray dif fraction.