In this paper a theoretical-evaluation is given of the absolute intens
ity and polarization of light emission from silicon devices due to con
duction-conduction (c-c) and valence-valence (v-v) direct transitions.
The matrix elements of the momentum operator between Bloch states hav
e been obtained from a full band-structure calculation performed with
the pseudopotential method. Results have been obtained by using both a
nalytical model distribution functions and realistic hot-carrier distr
ibutions obtained from Monte Carlo (MC) simulations based on the same
band model. They show a polarization degree of a few per cent, which s
hould be observable for these transitions.