A novel multiband theory of Bloch electron dynamics in homogeneous ele
ctric fields of arbitrary strength and time dependence is presented. I
n this formalism, the electric field is described through the use of t
he vector potential. Multiband coupling is treated through the use of
the Wigner-Weisskopf approximation, thus allowing for a Bloch electron
transition out of the initial band due to the power absorbed by the e
lectric field; also, the approximation ensures conservation of the tot
al transition probability over the complete set of excited bands. The
choice of the vector potential gauge leads to a natural set of extende
d time-dependent basis functions for describing Bloch electron dynamic
s in a homogeneous electric field; an associated basis set of localize
d, electric-field-dependent Wannier and related envelope functions are
developed and utilized in the analysis to demonstrate the inherent lo
calization manifest in Bloch dynamics in the presence of relatively st
rong electric fields. From the theory, a generalized Zener tunnelling
time is derived in terms of the applied uniform electric field and the
relevant band parameters. The analysis shows an electric-field-enhanc
ed broadening of the excited state probability amplitudes, thus result
ing in spatial lattice delocalization and the onset of smearing of dis
crete, Stark ladder and band-to-band transitions due to the presence o
f the electric field. In addition, the velocities of a Bloch oscillati
on will be observed only for the electron that is initially in a Bloch
state before Zener tunnelling. Further, the influence of electric fie
lds on resonant tunnelling structure is examined.