CALCULATION OF THE ROVIBRATIONAL B[-X EXCITATION SPECTRUM OF THE HE2CL2 CLUSTER

Authors
HERNANDEZ MI HALBERSTADT N
Citation
Mi. Hernandez et N. Halberstadt, CALCULATION OF THE ROVIBRATIONAL B[-X EXCITATION SPECTRUM OF THE HE2CL2 CLUSTER, The Journal of chemical physics, 100(10), 1994, pp. 7828-7831
Citations number
17
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
100
Issue
10
Year of publication
1994
Pages
7828 - 7831
Database
ISI
SICI code
0021-9606(1994)100:10<7828:COTRBE>2.0.ZU;2-B
Abstract
Three-dimensional quantum mechanical calculations on the rovibrational B<--X excitation spectrum of He2Cl2 are presented, and give excellent agreement with recent experiments. It is also shown that the spectrum can be fit by a rigid rotor if He exchange symmetry and overlapping H e-He bending excitations are taken into account.