A method of making quantitative measurements of atomic hydrogen levels
in diamond-like carbon (DLC) deposition plasmas is discussed. Multiph
oton laser induced fluorescence (MPLIF) is used to detect ground state
hydrogen atoms. The choice of excitation scheme to maximize the ratio
of fluorescence signal to ionization is explained. The MPLIF measurem
ents are calibrated using a combination of a flow reactor and titratio
n absolute standard, and a transferable hot filament atomic hydrogen s
ource specifically designed for installation in the DLC deposition sys
tem. The characteristics of the complete system are described, and ini
tial measurements in hot filament reactors are presented.