E. Gheeraert et al., CHARACTERIZATION OF DEFECTS IN BORON-IMPLANTED CHEMICALLY VAPOR-DEPOSITED DIAMOND FILMS BY ELECTRON-PARAMAGNETIC-RESONANCE AND CATHODOLUMINESCENCE, DIAMOND AND RELATED MATERIALS, 3(4-6), 1994, pp. 737-740
The same electron paramagnetic resonance active defects (C interactive
dangling bonds), with similar behaviour with respect to B dose before
(20 centres per B ion, amorphization threshold of 10(15) cm-2) and af
ter annealing at 800-degrees-C (concentration reduced by 95%), are cre
ated by B implantation in chemically vapour deposited polycrystalline
films and type Ha natural crystals of diamond. A broad 2.4 eV cathodol
uminescence band (substitutional B), appears only in polycrystalline f
ilms. Its intensity relative to the 2.92 eV band increases with the B
dose and decreases after annealing.