M. Werner et al., VERY-LOW RESISTIVITY AL-SI OHMIC CONTACTS TO BORON-DOPED POLYCRYSTALLINE DIAMOND FILMS, DIAMOND AND RELATED MATERIALS, 3(4-6), 1994, pp. 983-985
The effects on the contact resistivity of annealing Al-Si (99:1) conta
cts on diamond with different B concentrations have been investigated.
The change of the current-voltage characteristic from rectifying to o
hmic on lightly doped samples, and the drop of the contact resistivity
by orders of magnitude for more heavily B-doped samples after anneali
ng at 450-degrees-C in N2, are attributed to the formation of SiC at t
he metal-diamond interface. The existence of the SiC interface has bee
n verified by X-ray-induced photoelectron spectroscopy. In addition, t
he contact resistivity is a very sensitive function of doping at high
doping concentrations. Contact resistivities as low as about 10(-7) OM
EGA cm2 have been achieved.