POTASSIUM TRIISOPROPYLSILANETHIOLATE - VINYL AND ARYL SULFIDES THROUGH PD-CATALYZED CROSS-COUPLING

Authors
RANE AM MIRANDA EI SODERQUIST JA
Citation
Am. Rane et al., POTASSIUM TRIISOPROPYLSILANETHIOLATE - VINYL AND ARYL SULFIDES THROUGH PD-CATALYZED CROSS-COUPLING, Tetrahedron letters, 35(20), 1994, pp. 3225-3226
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
20
Year of publication
1994
Pages
3225 - 3226
Database
ISI
SICI code
0040-4039(1994)35:20<3225:PT-VAA>2.0.ZU;2-V
Abstract
Vinyl and aryl halides are efficiently converted, under Pd catalysis, with KSTIPS (1) to the corresponding silyl sulfides (2, 3). The naphth yl derivative was easily hydrolyzed to the mercaptan 4, or alkylated o r alkenylated to provide unsymmetrical sulfides (5, 6).