OXIDATION OF AN ALPHA,BETA-(EPOXYALKYL)TRIMETHYLSILANE WITH PYRIDINE OXIDES IN THE PRESENCE OF SILYLATING AGENTS - A FACILE ENANTIOSELECTIVE SYNTHESIS OF GLYCERALDEHYDE DERIVATIVES

Authors
RAUBO P WICHA J
Citation
P. Raubo et J. Wicha, OXIDATION OF AN ALPHA,BETA-(EPOXYALKYL)TRIMETHYLSILANE WITH PYRIDINE OXIDES IN THE PRESENCE OF SILYLATING AGENTS - A FACILE ENANTIOSELECTIVE SYNTHESIS OF GLYCERALDEHYDE DERIVATIVES, Tetrahedron letters, 35(20), 1994, pp. 3387-3390
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
20
Year of publication
1994
Pages
3387 - 3390
Database
ISI
SICI code
0040-4039(1994)35:20<3387:OOAAWP>2.0.ZU;2-B
Abstract
Trimethylsilyl glycidol derivatives 1 were oxidized with pyridine N-ox ides in the presence of silylating agents to give the corresponding gl yceraldehyde derivatives 3. Reaction of (alpha,beta-epoxyallcyl)silane s with N-oxides was studied.