HYDROBORATION INTRAMOLECULAR REDUCTION OF ALLYL KETONES WITH (DIISOPINOCAMPHEYL)BORANE - A CONVENIENT SYNTHESIS OF ENANTIOMERICALLY ENRICHED 1,4-DIOLS/

Authors
MOLANDER GA BOBBITT KL
Citation
Ga. Molander et Kl. Bobbitt, HYDROBORATION INTRAMOLECULAR REDUCTION OF ALLYL KETONES WITH (DIISOPINOCAMPHEYL)BORANE - A CONVENIENT SYNTHESIS OF ENANTIOMERICALLY ENRICHED 1,4-DIOLS/, Journal of organic chemistry, 59(10), 1994, pp. 2676-2678
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
59
Issue
10
Year of publication
1994
Pages
2676 - 2678
Database
ISI
SICI code
0022-3263(1994)59:10<2676:HIROAK>2.0.ZU;2-3
Abstract
The hydroboration of a variety of allyl ketones with (-)-(diisopinocam pheyl)borane precedes a highly stereoselective intramolecular reductio n of the ketone, providing a convenient procedure for the preparation of enantiomerically enriched alcohols.