STUDIES ON SULFINATODEHALOGENATION .29. THE SULFINATODEHALOGENATION OF PRIMARY POLYFLUOROALKYL IODIDES AND BROMIDES BY SODIUM DISULFITE

Authors
WU FH HUANG BN
Citation
Fh. Wu et Bn. Huang, STUDIES ON SULFINATODEHALOGENATION .29. THE SULFINATODEHALOGENATION OF PRIMARY POLYFLUOROALKYL IODIDES AND BROMIDES BY SODIUM DISULFITE, Journal of fluorine chemistry, 67(3), 1994, pp. 233-234
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
67
Issue
3
Year of publication
1994
Pages
233 - 234
Database
ISI
SICI code
0022-1139(1994)67:3<233:SOS.TS>2.0.ZU;2-2
Abstract
Using DMF, acetonitrile and alcohols as cosolvents, both polyfluoroalk yl iodides, such as Cl(CF2)nI (n = 4, 6, 8; 1a-c) and F(CF2)nI (n=6, 8 ; ld, e), and polyfluoroalkyl bromides, such as Cl(CF2)6Br (3b) and F( CF2)8Br (3e), react with sodium disulfite in neutral aqueous solution to give the corresponding sulfinates Cl(CF2)nSO2Na (n = 4, 6, 8; 2a-c) and F(CF2)nSO2Na (n = 6, 8; 2d, e) in good yield. In a similar manner , CF3CCl3 (4a) reacted with sodium disulfite to give CF3CCl2SO2Na (5a) .