H. Meinert et al., ON THE FORMATION AND CRYSTAL-STRUCTURES OF ALPHA-OMEGA-PERFLUORODIMORPHOLINOALKANES, Journal of fluorine chemistry, 67(3), 1994, pp. 235-240
The results of the electrochemical fluorination (ECF) of alpha,omega-d
imorpholinoalkanes with two to six CH-2 units between the morpholine r
ings are summarized. The crystal and molecular structures of the perfl
uorinated compounds are presented and discussed. Conclusions on the me
chanism of electrochemical fluorination are drawn based on an ionic me
chanism and a steric model.