S. Suenaga et al., INTERFACIAL REACTIONS BETWEEN SAPPHIRE AND SILVER-COPPER-TITANIUM THIN-FILM FILLER METAL, Journal of the American Ceramic Society, 80(2), 1997, pp. 439-444
Wetting and brazing studies of sputtering-deposited, submicrometer thi
n film filler metal in an Ag-Cu-Ti/Al2O3 system mere performed. The in
terfacial reaction layer between the filler metal and Al2O3 was invest
igated. It is possible to make a brazing joint even with a reaction la
yer of less than 100 nm thickness, Different types of interfacial reac
tion layers were observed when the Ti content in the filler metal was
varied. The Cu-Ti-O system compounds were observed in the samples with
high wetting capabilities, but not in the sample with low wetting cha
racteristics. It was found that these compounds are substances that pr
omote effective brazing.