HLORO(ETA-PENTAMETHYLCYCLOPENTADIENYL)RHODIUM(III) AND (EPSILON-PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM(III)] FROM BIS[CHLORO(1,5-CYCLOCTADIENE)RHODIUM(I) AND CHLORO(1,5-CYCLOCTADIENE)IRIDIUM(I)] OXIDATION, AND FORMATION OF TADIENE(ETA-PENTAMETHYLCYCLOPENTADIENYL)RHODIUM(I)

Authors
ELAMOURI H GRUSELLE M JAOUEN G
Citation
H. Elamouri et al., HLORO(ETA-PENTAMETHYLCYCLOPENTADIENYL)RHODIUM(III) AND (EPSILON-PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM(III)] FROM BIS[CHLORO(1,5-CYCLOCTADIENE)RHODIUM(I) AND CHLORO(1,5-CYCLOCTADIENE)IRIDIUM(I)] OXIDATION, AND FORMATION OF TADIENE(ETA-PENTAMETHYLCYCLOPENTADIENYL)RHODIUM(I), Synthesis and reactivity in inorganic and metal-organic chemistry, 24(3), 1994, pp. 395-400
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
24
Issue
3
Year of publication
1994
Pages
395 - 400
Database
ISI
SICI code
0094-5714(1994)24:3<395:HA(>2.0.ZU;2-J
Abstract
An efficient and rapid alternative route for high yield (>90%) synthes es of [CpMCl2]2 complexes (M = Rh, Ir) is described. This method invo lves the oxidation of M(I) to M(III) with HCI, from the commercially a vailable [MCI(cod)]2 compounds (cod = 1,5 cyclooctadiene). Repeating t he above experiments for M =Rh but using Na2CO3 instead of HCl, afford ed the known compound [CpRhCod].