CATIONIC COMPLEXES OF RUTHENIUM(III) AND RUTHENIUM(II) WITH TRIPHENYLPHOSPHINE AND OTHER LIGANDS

Authors
SARKER SC PODDAR RK
Citation
Sc. Sarker et Rk. Poddar, CATIONIC COMPLEXES OF RUTHENIUM(III) AND RUTHENIUM(II) WITH TRIPHENYLPHOSPHINE AND OTHER LIGANDS, Synthesis and reactivity in inorganic and metal-organic chemistry, 24(3), 1994, pp. 457-471
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
24
Issue
3
Year of publication
1994
Pages
457 - 471
Database
ISI
SICI code
0094-5714(1994)24:3<457:CCORAR>2.0.ZU;2-G
Abstract
First example of Ru(II) and Ru(III) complexes having five PPh3 groups coordinated to the metal, viz. [Ru(PPh3)5(ClO4)](ClO4)x, (x = 1 or 2) are reported. Some other cationic complexes, viz., [Ru(PPh3)4(CS)2] (C lO4)x, (x = 2 or 3), and [Ru(PPh3)(CS)2(Py2](ClO4)2 are also reported. All the cationic complexes are characterised by elemental analysis an d various physical measurements.