Dhr. Barton et W. Chavasiri, THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .36. STEREOSELECTIVITY STUDIES OF GIF-TYPE REACTIONS, Tetrahedron, 53(8), 1997, pp. 2997-3004
The stereoselectivity of various Gif-type reactions was evaluated usin
g trans-1,4-dimethylcyclohexane as a chemical probe. The results revea
led that these reactions were moderately stereoselective. The outcome
of the reactions was preferentially formed in the more stable equatori
al configuration. (C) 1997 Published by Elsevier Science Ltd.