S. Masuda et al., SURFACE-TREATMENT OF PLASTIC MATERIAL BY PULSE CORONA INDUCED PLASMA CHEMICAL PROCESS - PPCP, IEEE transactions on industry applications, 30(2), 1994, pp. 377-380
A novel plasma chemical process PPCP (Pulse Corona Induced Plasma Chem
ical Process) can produce copious active radicals in air under NTP (No
rmal Temperature and Pressure) by using an extremely fast rising narro
w high voltage pulse between corona electrodes and grounded counter el
ectrodes so that intense streamer coronas are generated. This provides
an effective means of surface treatment to a plastic material placed
between the two electrodes through generation of free bonds on the sur
face directed to the corona electrodes. Special features of this metho
d are that it can cope with a complex shape of the material to be trea
ted, and that it does not spark even at the periphery near the grounde
d counter electrode. This method is suitable for the surface treatment
of polypropylene bumpers so as to provide a strong adhesion of color
paint to it. The adhesion strength of a paint film is raised from zero
to ca. 1000 g/cm2 by PPCP treatment for 60 seconds.