T. Petrosky et I. Prigogine, QUANTUM CHAOS, COMPLEX SPECTRAL REPRESENTATIONS AND TIME-SYMMETRY BREAKING, Chaos, solitons and fractals, 4(3), 1994, pp. 311-359
As has been shown in recent publications. classical chaos leads to com
plex irreducible representation of the evolution operator (such as the
Perron-Frobenius operator for chaotic maps). Complex means that time
symmetry is broken (appearance of semi-groups) and irreducible that th
e representation can only be implemented by distribution functions (an
d not by trajectories). A somewhat similar situation occurs in Hamilto
nian nonintegrable systems with continuous spectrum (''Large Poincare
Systems'' LPS), both in classical and quantum mechanics.The eliminatio
n of Poincares divergences requires an extended formulation of dynamic
s on the level of distribution functions (or density matrices). This a
pplies already to simple situations such as potential scattering in th
e case of persistent interactions. There appear characteristic delta-f
unction singularities in the density matrices in momentum representati
on. Our theory predicts then dissipative processes corresponding to th
e destruction of invariants of motion through Poincare resonances. Thi
s prediction is quantitative agreement with extensive numerical simula
tions presented here. We concentrate in this paper on potential scatte
ring. We discuss also briefly a simple model of a many-body system (th
e so called ''perfect Lorentz gas''). In both cases we obtain irreduci
ble spectral representations which we consider as the signature of ''c
haos''. We solve the eigenvalue problem for the Liouville-von Neumann
operator for the class of singular density matrices corresponding to p
ersistent scattering. This leads to a complex spectral representation
in which cross sections appear as eigenvalues. Our previous results [s
ee our previous paper in Chaos, Solitons & Fractals (1991)] obtained b
y ''subdynamics theory'' are now derived through the solution of the e
igenvalue problem for singular distributions. Our results can be teste
d by numerical simulations. Again the agreement is excellent. Note tha
t our results cannot be derived from conventional quantum theory for p
robability amplitudes. We have therefore here a simple example of a qu
antum theory which goes beyond the traditional Schrodinger formulation
. As already mentioned, our theory is formulated on the level of densi
ty matrices. Wave functions corresponding to persistent scattering (an
d therefore to singular density matrices) ''collapse'' as the result o
f Poincare divergences. We obtain therefore a unified formulation of q
uantum theory without any appeal to extra dynamical concepts (such as
many worlds, influence of environment,...). The appearance of chaos fo
r LPS through the formulation of complex irreducible representations o
n the level of density matrices solves therefore not only the ''time p
aradox'' as it introduces time symmetry breaking on the microscopic le
vel, but eliminates also the old standing epistemological problems of
quantum theory associated to measurement and to decoherence.