SYNTHETIC STUDIES ON SPINOSYN-A - CONVENIENT ENANTIOSELECTIVE CONSTRUCTION OF A SUITABLY FUNCTIONALIZED TRANS,ANTI,CIS-DECAHYDRO-AS-INDACENE INTERMEDIATE VIA [3.3] SIGMATROPY AND DOUBLE CONFIGURATIONAL INVERSION

Authors
PAQUETTE LA GAO ZL NI ZJ SMITH GF
Citation
La. Paquette et al., SYNTHETIC STUDIES ON SPINOSYN-A - CONVENIENT ENANTIOSELECTIVE CONSTRUCTION OF A SUITABLY FUNCTIONALIZED TRANS,ANTI,CIS-DECAHYDRO-AS-INDACENE INTERMEDIATE VIA [3.3] SIGMATROPY AND DOUBLE CONFIGURATIONAL INVERSION, Tetrahedron letters, 38(8), 1997, pp. 1271-1274
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
8
Year of publication
1997
Pages
1271 - 1274
Database
ISI
SICI code
0040-4039(1997)38:8<1271:SSOS-C>2.0.ZU;2-8
Abstract
An enantioselective route to the decahydro-as-indacene 15 is described . Anionic oxy-Cope rearrangement of alcohol 5 initiates the sequence, which capitalizes on thermodynamics to control ultimate elaboration of the four key stereogenic centers resident in the several intermediate s. (C) 1997 Elsevier Science Ltd.