BIS AND TETRAKIS(6-METHYL-1,4-DITHIAFULVEN-6-YL) SUBSTITUTED TETRATHIAFULVALENES (TTF) AND THEIR VINYLOGS AS NOVEL PI-DONORS

Authors
LERICHE P BELYASMINE A SALLE M GORGUES A JUBAULT M GARIN J ORDUNA J
Citation
P. Leriche et al., BIS AND TETRAKIS(6-METHYL-1,4-DITHIAFULVEN-6-YL) SUBSTITUTED TETRATHIAFULVALENES (TTF) AND THEIR VINYLOGS AS NOVEL PI-DONORS, Tetrahedron letters, 38(8), 1997, pp. 1399-1402
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
8
Year of publication
1997
Pages
1399 - 1402
Database
ISI
SICI code
0040-4039(1997)38:8<1399:BATST>2.0.ZU;2-P
Abstract
The synthesis of highly extended and sulfur rich tetrathiafulvalene de rivatives, designed to avoid any internal cyclisation during their sub sequent electrooxidation, is described Their pi-donating ability is co nfirmed by cyclic voltammetry, as well as the good stability of each o f their oxidized species (up to an hexacationic state in one case). (C ) 1997 Elsevier Science Ltd.