Rb. Cinque et Jw. Morris, THE EFFECT OF GOLD-NICKEL METALLIZATION MICROSTRUCTURE ON FLUXLESS SOLDERING, Journal of electronic materials, 23(6), 1994, pp. 533-539
Gold plating is used in the microelectronics industry to maintain the
wettability of metal substrates. The nature of wetting during solderin
g of gold plated metals is discussed, and the results of experiments o
n the fluxless wettability and oxidation of gold plated nickel are des
cribed. The results suggest that electrodeposition of a thin gold plat
e (0.14 mum) and the concurrent reduction of nickel oxide produce a go
ld-nickel system which will wet without flux. Oxidation of nickel was
observed to occur via nickel out-diffusion and by direct exposure of t
he substrate through pinhole plating defects. Auger chemical analysis
indicates that pinholes do not produce oxidation of the surrounding su
bstrate area.