SYNTHESIS AND CHARACTERIZATION OF (Z)-1-[2-(TRIARYLSTANNYL)VINYL]-CYCLO-HEXANOLS AND THEIR ARYLHALOSTANNYL DERIVATIVES

Authors
XIN FF LIN SX JIE FY PAN H GIELEN M KAYSER F WILLEM R
Citation
Ff. Xin et al., SYNTHESIS AND CHARACTERIZATION OF (Z)-1-[2-(TRIARYLSTANNYL)VINYL]-CYCLO-HEXANOLS AND THEIR ARYLHALOSTANNYL DERIVATIVES, Zeitschrift fur anorganische und allgemeine Chemie, 620(6), 1994, pp. 1006-1010
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
6
Year of publication
1994
Pages
1006 - 1010
Database
ISI
SICI code
0044-2313(1994)620:6<1006:SACO(>2.0.ZU;2-J
Abstract
1-Ethynyl-1-cyclohexanol reacts with a triaryltin hydride Ar3SnH (Ar = phenyl, p-tolyl) and generates the corresponding (Z)-1-[2-(triarylsta nnyl)vinyl]-1-cyclohexanol. The product obtained reacts with one or tw o equivalents of halogen (ICl or I2) to form the associated (Z)-1-[2-( diarylhalostannyl)-vinyl]-1-cyclohexanol or (Z)-1-[2-(aryldihalostanny l)vinyl]-1-cyclohexanol, respectively. All compounds were characterize d by elemental analysis, H-1, C-13, Sn-119 NMR and Mossbauer spectrosc opy.