OXIDATIVE FLUORINATION OF (CF3)(R)CS(O2)C (CF3)(R)S (R=CF3, CL) AND THE CRYSTAL-STRUCTURE OF (CF3)(CL)CS(O2)C(CF3)(CL)SF-(ASF6)

Authors
MINKWITZ R BACK B PREUT H
Citation
R. Minkwitz et al., OXIDATIVE FLUORINATION OF (CF3)(R)CS(O2)C (CF3)(R)S (R=CF3, CL) AND THE CRYSTAL-STRUCTURE OF (CF3)(CL)CS(O2)C(CF3)(CL)SF-(ASF6), Zeitschrift fur anorganische und allgemeine Chemie, 620(6), 1994, pp. 1125-1131
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
6
Year of publication
1994
Pages
1125 - 1131
Database
ISI
SICI code
0044-2313(1994)620:6<1125:OFO(((>2.0.ZU;2-R
Abstract
Oxidative fluorination of (CF3)(R)CS(O2)C(CF3)(R)S (R = CF3, Cl) with XeF+MF6- (M = As, Sb) in anhydrous HF results in formation of monofluo rsulfonium hexafluorometalates. The salts are characterized by vibrati onal, NMR, and mass spectra. (CF3)(CI)CS(O2)C(CF3)(Cl)SF+AsF6- crystal lizes in the monoclinic space group P2(1)/c with a = 9.955(10) angstro m, b = 11.050(5) angstrom, c = 12.733(15) angstrom, beta = 97.77(5)-de grees, and Z = 4.