The reaction between the Ba-Cu-O melt (with a Ba to Cu ratio of 3-5 or
3-7) used for crystal pulling of Y-123 and several prospective crucib
le materials (MgO, Y2O3, Al2O3, and YSZ) has been investigated by dipp
ing these materials i-to the melt at 985-degrees-C and 1050-degrees-C
in air. For comparison, MgO, YSZ, LaAlO3, and SrTiO3 single crystals w
ere also investigated. In the case of MgO single crystals, no wetting
or reactive layer has been observed, although with increasing time an
increasing amount of MgO has been dissolved into the melt. The contact
angle between melt and MgO single crystal can be estimated to be abou
t 40-degrees, assuming a surface tension of 0.3 N/m. For all other mat
erials, increasing time was accompanied by increasing wetting and/or a
n increasing reaction layer. For MgO polycrystals increased wetting wi
th increasing time has been observed. For example, it takes about 30 m
in to wet the first 10 mm. The melt completely permeates samples with
an apparent density of up to 85%. However, the permeated depth becomes
very thin in samples with an apparent 95% density. It was found that
Y2O3 is a better barrier to the melt at lower densities because even a
t 85% density the permeated layer is very thin, but the surface wettin
g occurs at a slightly faster rate for Y2O3 than for MgO.