Preheating potatoes at 50 to 80-degrees-C has a firming effect on the
cooked potato tissue. This effect is particularly pronounced at a preh
eating temperature of 60 to 70-degrees-C followed by cooling. Several
theories have been presented in the literature to explain this firming
effect: retrogradation of starch, leaching of amylose, stabilization
of the middle lamellae and cell walls by the activation of the pectin
methylesterase (PME) enzyme, and by the release of calcium from gelati
nized starch and the formation of calcium bridges between pectin molec
ules. Most probably, none of these theories alone can explain the phen
omenon and more than one mechanism seems to be involved. Some of these
mechanisms seem to be interdependent. As an example, calcium could be
considered as a link all the way through release after starch gelatin
ization to cross-linking pectin substances in the cell wall and the mi
ddle lamellae, which has been demethylated by the PME enzyme. More res
earch and ''clear cut'' experiments re needed in order to elucidate th
e role of each mechanism, especially which of them is the main contrib
utor to the process of firming. Most probably, the calcium-pectin-PME
mechanism plays a secondary role, that is, it only retards the collaps
e of the tissue structure that would otherwise occur during the final
heating without preheating, and it is not the main factor of firmness.