TEMPERATURE-DEPENDENT ELECTRONIC-STRUCTURE OF GADOLINIUM

Citation
W. Nolting et al., TEMPERATURE-DEPENDENT ELECTRONIC-STRUCTURE OF GADOLINIUM, Zeitschrift fur Physik. B, Condensed matter, 94(4), 1994, pp. 409-421
Citations number
49
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
07223277
Volume
94
Issue
4
Year of publication
1994
Pages
409 - 421
Database
ISI
SICI code
0722-3277(1994)94:4<409:TEOG>2.0.ZU;2-G
Abstract
We investigate the electronic structure of the ferromagnetic 4f-metal Gadolinium by use of a many-body evaluation of a generalized model of magnetism, the one-particle part of which is derived from an ASW-LSDA bandstructure calculation. A striking temperature-dependence of the co nduction band states is traced back to a 4f-(5d, 6s) interband exchang e. The conduction electron polarization (0.63 mu(B) at T=0) decreases for T --> T(c) very similar to the 4f-magnetization. A red shift of th e lower up-T-band edge of about 0.25 eV appears upon cooling from T=T( c) to T=0. - The quasiparticle band-structure exibits a remarkable non uniform magnetic behaviour at different positions in the Brillouin zo ne, and in particular for different subbands. Weakly correlated (''s-l ike'') dispersions show a ''Stoner-like'' T-dependence of the exchange splitting. On the other hand, stronger correlated (''d-like'') disper sions split below T(c) into four branches, two for each spin direction . Their T-dependence mainly concerns the spectral weights of the quasi particle peaks and not so much the energetic positions. An exchange ca used splitting remains even for T> T(c).