Auger spectrometry has been used to study the effects of various types
of surface treatment on the degree of disorder and the stoichiometry
of 6H-SiC(0001BAR). The methods studied were ion etching in a plasma o
f argon and nitrogen, reactive ion etching in a plasma of SF6 and CF4,
chemical etching, and the chemical removal of an oxide from a test sa
mple oxidized beforehand. The results show that the ion etching result
s in a complete destruction of Si-C bonds on the surface. Processing b
y all the other methods results in primarily a disruption of the stoic
hiometry. The effect of heating and electron bombardment on the C/Si r
atio after the processing was studied. It was shown that the change in
stoichiometry during heating depends essentially on the preliminary p
rocessing method.