A size effect involving the intervalley distance L(upsilon) and the co
oling length L(epsilon) in the thermal emf of multivalley semiconducto
rs of the n-Si type is examined theoretically. The method used involve
s seeking solutions for the symmetric part of the distribution functio
n f0(alpha) (epsilon, r, t) in the valleys as an expansion in eigenfun
ctions of an operator responsible for the quasielastic intervalley sca
ttering. In thin samples, the thermal emf becomes anisotropic and may
be several times the thermal emf of a bulk sample.