INTRAMOLECULAR HOMOLYTIC SUBSTITUTIONS .2 0. INFLUENCE OF THE NATURE OF THE PEROXIDE FUNCTION ON INDUCED DECOMPOSITION OF DELTA-UNSATURATEDPEROXIDES

Authors
MAILLARD B LUBEIGT X BOURGEOIS MJ MONTAUDON E
Citation
B. Maillard et al., INTRAMOLECULAR HOMOLYTIC SUBSTITUTIONS .2 0. INFLUENCE OF THE NATURE OF THE PEROXIDE FUNCTION ON INDUCED DECOMPOSITION OF DELTA-UNSATURATEDPEROXIDES, Canadian journal of chemistry, 72(4), 1994, pp. 1094-1098
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Canadian journal of chemistry → ACNP
ISSN journal
00084042
Volume
72
Issue
4
Year of publication
1994
Pages
1094 - 1098
Database
ISI
SICI code
0008-4042(1994)72:4<1094:IHS.0I>2.0.ZU;2-D
Abstract
Induced decomposition of delta-unsaturated peroxidic derivatives CH2=C H(CH2)(3)OY (Y = OtBu, OCMe(2)Ph, OCOEt, OCMe(2)OMe) in various solven ts yields a heterocycte and, in some cases, a peroxidic adduct. Intram olecular homolytic substitution (S(H)i) leading to the cyclic ether is highly dependent on the thermal stability of the peroxidic linkage. T he rate constant was determined at 60 degrees C for Y = OtBu, OCMe(2)P h.