ABSORPTION AND FLUORESCENCE OF TL ATOMS IN RARE-GAS MATRICES

Authors
WURFEL BE THOMA A SCHALLMOSER G LAMMERS A BONDYBEY VE
Citation
Be. Wurfel et al., ABSORPTION AND FLUORESCENCE OF TL ATOMS IN RARE-GAS MATRICES, The Journal of chemical physics, 100(11), 1994, pp. 8003-8009
Citations number
33
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
100
Issue
11
Year of publication
1994
Pages
8003 - 8009
Database
ISI
SICI code
0021-9606(1994)100:11<8003:AAFOTA>2.0.ZU;2-B
Abstract
Tl containing Ar, Kr, and Xe matrices were produced by electrode sputt ering in a self-igniting pulsed-discharge unit. The absorption and las er-induced fluorescence spectra of the thallium atoms have been invest igated. The results are compared with our recent observations of gas p hase diatomic thallium-rare gas (Tl-Rg) clusters. The observed linewid ths, shifts, and relaxation dynamics are qualitatively interpreted on the basis of the pairwise Tl-Rg interaction potentials.