LANTHANIDE-TUNGSTEN HETEROBIMETALLIC COMPLEXES VIA SIGMA-BOND METATHESIS

Authors
RADU NS GANTZEL PK TILLEY TD
Citation
Ns. Radu et al., LANTHANIDE-TUNGSTEN HETEROBIMETALLIC COMPLEXES VIA SIGMA-BOND METATHESIS, Journal of the Chemical Society, Chemical Communications, (10), 1994, pp. 1175-1176
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1994
Pages
1175 - 1176
Database
ISI
SICI code
0022-4936(1994):10<1175:LHCVSM>2.0.ZU;2-1
Abstract
Reactions of [{Ln(C(5)Me(5))(2)H}(2)] (Ln = Y, Sm) with [W(C5H5)(2)H-2 ] afford the sigma-bond metathesis products [(C(5)Me(5))(2)Ln(mu-eta(1 ), eta(5)-C5H4)(mu-H)(2)W(C5H5)], via dehydrocoupling between the Ln-H bond and the C-H (but not the weaker W-H) bond of [W(C5H5)(2)H-2].