DIRECT CONVERSION OF CARBON-MONOXIDE TO A COORDINATED SECONDARY ALCOHOL DERIVATIVE BY A THORIUM PHOSPHIDO COMPLEX

Authors
EDWARDS PG HURSTHOUSE MB MALIK KMA PARRY JS
Citation
Pg. Edwards et al., DIRECT CONVERSION OF CARBON-MONOXIDE TO A COORDINATED SECONDARY ALCOHOL DERIVATIVE BY A THORIUM PHOSPHIDO COMPLEX, Journal of the Chemical Society, Chemical Communications, (10), 1994, pp. 1249-1250
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1994
Pages
1249 - 1250
Database
ISI
SICI code
0022-4936(1994):10<1249:DCOCTA>2.0.ZU;2-Y
Abstract
The homoleptic eight coordinate thorium dialkylphosphide, Th[P(CH(2)CH (2)PMe(2))(2)](4) 1 reacts with carbon monoxide to give the first repo rted double insertion product where CO is incorporated into a coordina ted secondary alcohol derivative by the coupling of two dialkyl phosph ide groups at the same carbon atom.