ANION RECOGNITION BY NOVEL RUTHENIUM(II) BIPYRIDYL CALIX[4]ARENE RECEPTOR MOLECULES

Authors
BEER PD CHEN Z GOULDEN AJ GRIEVE A HESEK D SZEMES F WEAR T
Citation
Pd. Beer et al., ANION RECOGNITION BY NOVEL RUTHENIUM(II) BIPYRIDYL CALIX[4]ARENE RECEPTOR MOLECULES, Journal of the Chemical Society, Chemical Communications, (10), 1994, pp. 1269-1271
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1994
Pages
1269 - 1271
Database
ISI
SICI code
0022-4936(1994):10<1269:ARBNRB>2.0.ZU;2-2
Abstract
Exotic calix[4]arene mono- and di-topic anion receptors containing one and two ruthenium(II) bipyridyl moieties have been prepared and shown by H-1 NMR and CV to bind and electrochemically recognise halide, dih ydrogen phosphate and hydrogen sulphate anions. The monotopic calix[4] arene anion receptor 8 selectively electrochemically recognises H2PO4- in the presence of tenfold excess amounts of HSO4- and Cl-.