SYNTHETIC STUDIES ON TAXOL .2. BETA-FRAGMENTATION OF ALKOXY RADICALS IN MEDIUM-SIZED CARBOCYCLE SYNTHESIS

Authors
OH JH LEE JH JIN SJ CHA JK
Citation
Jh. Oh et al., SYNTHETIC STUDIES ON TAXOL .2. BETA-FRAGMENTATION OF ALKOXY RADICALS IN MEDIUM-SIZED CARBOCYCLE SYNTHESIS, Tetrahedron letters, 35(21), 1994, pp. 3449-3452
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
21
Year of publication
1994
Pages
3449 - 3452
Database
ISI
SICI code
0040-4039(1994)35:21<3449:SSOT.B>2.0.ZU;2-5
Abstract
An efficient excision of the keto bridge present in tricyclo[4.3.1.1(2 ,5)]undecanones or tricyclo[5.3.1.1(2,6)]dodecanones has been accompli shed by beta-fragmentation of an alkoxy radical under the procedure of Suarez [PhI(OAc)(2)-I-2].