SODIUM TRIMETHYLSILANETHIOLATE IN NOVEL CYCLIZATIONS FOR SYNTHESIS OFAROMATIC HETEROTRICYCLIC COMPOUNDS

Authors
LAI LL LIN PY HUANG WH SHIAO MJ HWU JR
Citation
Ll. Lai et al., SODIUM TRIMETHYLSILANETHIOLATE IN NOVEL CYCLIZATIONS FOR SYNTHESIS OFAROMATIC HETEROTRICYCLIC COMPOUNDS, Tetrahedron letters, 35(21), 1994, pp. 3545-3546
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
21
Year of publication
1994
Pages
3545 - 3546
Database
ISI
SICI code
0040-4039(1994)35:21<3545:STINCF>2.0.ZU;2-4
Abstract
A new method was developed for synthesis of aromatic heterotricyclic c ompounds in 50-64% yields from diaryls bearing a functionality includi ng OMe, COOMe, and CN, and a leaving group (i.e., F and OMe) by use of Me(3)SiSNa in 1,3-dimethyl-2-imidazolidinone at 120-150 degrees C.